Publications
• Global Kinetic-Thermodynamic Responses: Derivation of a General Non-Linear Equation and Demonstrations on Chemical Reactions.
Eduardo Garcia-Padilla*; Guanqi Qiu.* https://chemrxiv.org/engage/chemrxiv/article-details/67e1977dfa469535b965c232
• Exceptions, Paradoxes, and Their Resolutions in Chemical Reactivity
Qiu, G.* J. Org. Chem. 2024, asap. https://pubs.acs.org/doi/10.1021/acs.joc.4c02246
• Intrinsic Barrier Width and its Role in Chemical Reactivity.
Qiu, G.*; Schreiner, P. R*. Intrinsic Barrier Width and its Role in Chemical Reactivity. ACS Cent. Sci. 2023, 2129−2137. The Intrinsic Barrier Width and Its Role in Chemical Reactivity | ACS Central Science
Prior to MPI-Kofo
• Isotopic Fractionation as a Mechanistic Probe in Light-Driven C–H Bond Exchange Reactions.
Qiu, G.; Ni, C. L.; Knowles, R. R.* J. Am. Chem. Soc. 2023, 145, 11537. Isotopic Fractionation as a Mechanistic Probe in Light-Driven C–H Bond Exchange Reactions | Journal of the American Chemical Society (acs.org)
• Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis.
Murray, P. R. D.; Cox, J. H.; Chiappini, N. D.; Roos, C. B.; McLoughlin, E. A.; Hejna, B. G.; Nguyen, S. T.; Ripberger, H. H.; Ganley, J. M.; Tsui, E.; Shin, N. Y.; Koronkiewicz, B.; Qiu, G.; Knowles, R. R.* Chem. Rev. 2022, 122, 2017. Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis | Chemical Reviews (acs.org)
• Understanding Chemoselectivity in Proton-Coupled Electron Transfer: A Kinetic Study of Amide and Thiol Activation.
Qiu, G.; Knowles, R. R.* J. Am. Chem. Soc. 2019, 141, 16574. Understanding Chemoselectivity in Proton-Coupled Electron Transfer: A Kinetic Study of Amide and Thiol Activation | Journal of the American Chemical Society (acs.org)
• Rate-Driving Force Relationships in the Multisite-PCET Activation of Ketones.
Qiu, G.; Knowles, R. R.* J. Am. Chem. Soc. 2019, 141, 2721. Rate–Driving Force Relationships in the Multisite Proton-Coupled Electron Transfer Activation of Ketones | Journal of the American Chemical Society (acs.org)
• An Alternative Fragmentation Pathway of 5H‐1, 4, 2‐Oxathiazoles Under Basic Conditions.
Yong, F.F., Hewitt, R.J., Ong, M.J., Qiu, G. and Burkett, B.A.* ChemistrySelect, 2017, 2, 7961. An Alternative Fragmentation Pathway of 5H‐1,4,2‐Oxathiazoles Under Basic Conditions - Yong - 2017 - ChemistrySelect - Wiley Online Library.